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Because
there is a component in nylon material called amido-nhco-has polarity, its
molecular formula: c24h20clno3 molecular weight: 405.87, the content of this
component is directly related to the size of water absorption. When selecting
materials, we should pay attention to the structure of nylon material to avoid
the failure of product design due to high water absorption.
The main component of nylon is
polyamide, whose amide group nhco has polarity, which makes nylon have
double-sided properties of water absorption and dehydration. Nylon without
water absorption is brittle and easy to break, but its physical properties will
appear after water absorption. Nylon products will be brittle and fracture
after long-term drying and dehydration in low temperature environment, which
will shorten the service life of nylon. Therefore, it is necessary to know that
nylon molding PA6 is the PA with the highest water absorption. In the
experiment of polycondensation, the molecular weight of nylon is about 5000.
The molecular weight of the polymer reached 10000-20000. Because nylon 6 has
good fluidity, its molecular weight is less than nylon, so the intermolecular
gap is large, so its water absorption is high
1.
Analysis of the reasons for the water boiling of nylon parts: nylon is a kind
of crystalline thermoplastic material, which is easy to absorb water and
contains hydrophilic group (acylamino). For crystalline polymer, in the
injection molding process, the rapid cooling makes the material unable to
naturally crystallize and set, so that there is a strong internal stress in the
material. For nylon material without "tempering" treatment, the In
the interior, the macromolecules will still tend to move towards natural
orientation and crystallization after finalization, which will further
aggravate the internal stress of the material. Therefore, the nylon parts
without water boiling process are very brittle, which is easy to collapse or
fracture when subjected to external force. Then, if the formed nylon macromolecules
are naturally oriented and crystallized, how about eliminating the internal
stress as much as possible In fact, the boiling and boiling process of nylon is
similar to the setting of our metal "tempering" process. That is to
let nylon parts soak in a certain water temperature, so that the internal
macromolecules tend to the natural orientation as much as possible and reach
the balance of internal crystallization and crystallization, so as to eliminate
the internal stress. On the outside, the toughness of nylon parts is greatly
enhanced, and the brittleness is basically eliminated Why cooking with water?
That's because nylon contains acylamino group, a hydrophilic group, which makes
nylon easy to absorb water, but when nylon absorbs a certain amount of water,
it helps its internal macromolecule orientation and crystallization movement.
The best temperature and time for cooking nylon parts: 90-100 ℃, 2-3 hours. If it's
lower than 90 degrees, the effect is not good. If it's more than 3 hours, there
will be no better result. In terms of cost performance, The above process
conditions are the best 。